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Definition

A poker hand in Texas hold 'em, consisting of two nine cards.

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Origins

A pun on nine nine and German nein nein (“no, no”).

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How People Actually Use It

In Texas holdem, when a player is dealt pocket nines, he is said to be holding a german virgin.

"Guy: Hey you dumb kraut, lets have sex. German Virgin: NEIN, NEIN!!!"

Source: Urban Dictionary